https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk
.trig | .trig.txt | .jelly | .jelly.txt | .jsonld | .jsonld.txt | .nq | .nq.txt | .xml | .xml.txt
@prefix this: <https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk> .
@prefix sub: <https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/> .
@prefix np: <http://www.nanopub.org/nschema#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix npx: <http://purl.org/nanopub/x/> .
@prefix dc: <http://purl.org/dc/terms/> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .
sub:Head {
this: a np:Nanopublication;
np:hasAssertion sub:assertion;
np:hasProvenance sub:provenance;
np:hasPublicationInfo sub:pubinfo .
}
sub:assertion {
<https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01> a <https://w3id.org/delphi/ontology/Claim>;
dc:description "The rupture strength of hydrogen-bond assemblies is set by geometric confinement: clusters of at most 3–4 H-bonds break concurrently, even when a much larger number of H-bonds is loaded in uniform shear.";
dc:type "mathematical-law";
<http://www.w3.org/2000/01/rdf-schema#comment> "Notation basis: The bound is stated in the abstract; its derivation (balance of elastic energy stored in the strand against H-bond energy, giving a critical strand length) is in the full text, not vendored.";
<http://www.w3.org/2000/01/rdf-schema#label> "At most three to four hydrogen bonds break together, whatever the assembly size";
<http://www.w3.org/2004/02/skos/core#notation> "b_{\\mathrm{rupture}} \\le 3\\text{–}4 \\quad \\text{for any } N \\ge b \\text{ H-bonds under uniform shear}";
<https://w3id.org/delphi/ontology/context> "Sinan Keten et al., “Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale”, Nano Letters 8, 743-748 (2008), doi:10.1021/nl0731670; Abstract. Scope: Beta-sheet H-bond assemblies under shear, in theory and full-atomistic MD in explicit solvent" .
}
sub:provenance {
<https://doi.org/10.1021/nl0731670> a <https://schema.org/CreativeWork>;
dc:bibliographicCitation "Sinan Keten, Markus J. Buehler. Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale. Nano Letters 8, 743-748 (2008). doi:10.1021/nl0731670";
dc:creator "Sinan Keten, Markus J. Buehler";
dc:date "2008"^^xsd:gYear;
dc:identifier "doi:10.1021/nl0731670", "pmid:18269263";
dc:title "Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale" .
<https://w3id.org/delphi/resource/agent/delphisci-buehler-protein-materials-extractor>
a prov:SoftwareAgent;
<http://www.w3.org/2000/01/rdf-schema#label> "delphisci buehler-protein-materials claim extractor";
prov:actedOnBehalfOf <https://orcid.org/0009-0007-4948-9192>;
<https://w3id.org/delphi/ontology/usesModel> <https://w3id.org/delphi/resource/model/claude-fable-5.1> .
<https://w3id.org/delphi/resource/model/claude-fable-5.1> a <https://w3id.org/delphi/ontology/LanguageModel>;
<http://www.w3.org/2000/01/rdf-schema#label> "Claude Fable 5.1" .
sub:assertion prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-buehler-protein-materials-extractor>;
prov:wasDerivedFrom <https://doi.org/10.1021/nl0731670>, sub:quote;
prov:wasGeneratedBy sub:extraction .
sub:extraction a prov:Activity;
prov:qualifiedAssociation sub:extractionPlan;
prov:used <https://github.com/fractastical/delphisci/blob/b89a0890bee05ef18f8202387085854fac3ca776/claim-sources/buehler-protein-materials/inputs/sources.json>,
<https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json>;
prov:wasAssociatedWith <https://w3id.org/delphi/resource/agent/delphisci-buehler-protein-materials-extractor> .
sub:extractionPlan prov:hadPlan <https://github.com/fractastical/delphisci/blob/b89a0890bee05ef18f8202387085854fac3ca776/claim-sources/buehler-protein-materials/build/generate.mjs> .
sub:quote a prov:Entity;
<http://www.w3.org/2000/01/rdf-schema#comment> "Quoted from the published abstract as returned by Europe PMC (2008-hbond-confinement.abstract.txt, sha256 880dc02fe6911c5cdb1ab49189a7e6b0f6dc782017ec700c7a498afd4193e722); the full text was not read (not in Europe PMC open-access subset). Checked by build/check.py.";
prov:hadPrimarySource <https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json>;
prov:wasQuotedFrom <https://doi.org/10.1021/nl0731670>;
<https://schema.org/text> "We discover that the rupture strength of H-bond assemblies is governed by geometric confinement effects, suggesting that clusters of at most 3-4 H-bonds break concurrently, even under uniform shear loading of a much larger number of H-bonds." .
sub:sourceChecksum <http://spdx.org/rdf/terms#algorithm> <http://spdx.org/rdf/terms#checksumAlgorithm_sha256>;
<http://spdx.org/rdf/terms#checksumValue> "880dc02fe6911c5cdb1ab49189a7e6b0f6dc782017ec700c7a498afd4193e722";
<http://www.w3.org/2000/01/rdf-schema#comment> "Checksum of the vendored text file inputs/2008-hbond-confinement.abstract.txt, not of the publisher's copy." .
<https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json>
a prov:Entity;
<http://spdx.org/rdf/terms#checksum> sub:sourceChecksum;
<http://www.w3.org/2000/01/rdf-schema#label> "Abstract of Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale, as read";
<https://schema.org/about> <https://doi.org/10.1021/nl0731670> .
}
sub:pubinfo {
<https://w3id.org/delphi/resource/domain/buehler-protein-materials> <http://www.w3.org/2000/01/rdf-schema#label>
"buehler-protein-materials" .
this: dc:created "2026-11-08T04:38:11.893Z"^^xsd:dateTime;
dc:creator <https://orcid.org/0009-0007-4948-9192>;
dc:license <https://creativecommons.org/licenses/by/4.0/>;
npx:hasNanopubType <https://w3id.org/delphi/ontology/Claim>;
npx:introduces <https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01>;
<http://www.w3.org/2000/01/rdf-schema#label> "Sinan Keten et al. 2008 claim: At most three to four hydrogen bonds break together, whatever the assembly size";
<https://w3id.org/delphi/ontology/domain> <https://w3id.org/delphi/resource/domain/buehler-protein-materials> .
sub:sig npx:hasAlgorithm "RSA";
npx:hasPublicKey "MIIBIjANBgkqhkiG9w0BAQEFAAOCAQ8AMIIBCgKCAQEAyFHtPB6p0mCjDozxlOY9CmO3nBm7Te3jFbXyLmM+G1tGe47Da0jYIbhkl9Oo1ZjxmCa3LCwlEqK8gj6hEIcL4ahW30JXh9HycfKVk1bugkzMEV15tJdTzAU3sGMFnbNsn43xY2LFLy45tApkRm5byEiM7oRRrooIdwoQKnP4Wzq/bfAoJ9qvW+MGkelyOTd1jbSt+KfmT7xKmDfWzAHddUlWwMX2QJOLxDaffOteTop6ZRgPiNmPJKA/S62Gac9XtSYT3oDkZ6/nr5cxxNLpOyxTf5FPISiCe11xYO/unYjY+mwnOfA8yhJIyx1l0O9I0vpOpn+E5TvyHJV+oSTrvwIDAQAB";
npx:hasSignature "XASB771nVEK/qy8id2Iy3HOtjkwNzGkjPJRsUArzNKMxcEPmruo/nFRJ/kMHDK3GhXxuk1kLl7MNJ7REAlK8woGdpaRK7prQjOX74P66PBaJZyW/iHxWepnkWpS6HbdRpeRbWeNR/EdVpybLnBHVlPGpqxHJhH18oejai06HqvlmAhOHZ0fQbOHS9up/UmzTytyI5u9plM0nvUnfzLnNv8GnMvoittUolC+s/ShLj2fu4nnUFvW3flY0teDyuu2SVGMNUjRFiAkXXwGmMkAbq0gyg2mYrgwe/vAR4kch7+A1Vt8K8L2kFdv9lP4KbJSUTLexH4Q1WJ6BhBJkFsZPYQ==";
npx:hasSignatureTarget this:;
npx:signedBy <https://orcid.org/0009-0007-4948-9192> .
}