https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/Head https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://www.nanopub.org/nschema#hasAssertion https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/assertion https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://www.nanopub.org/nschema#hasProvenance https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/provenance https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://www.nanopub.org/nschema#hasPublicationInfo https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/pubinfo https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://www.w3.org/1999/02/22-rdf-syntax-ns#type http://www.nanopub.org/nschema#Nanopublication https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/assertion https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01 http://purl.org/dc/terms/description The rupture strength of hydrogen-bond assemblies is set by geometric confinement: clusters of at most 3–4 H-bonds break concurrently, even when a much larger number of H-bonds is loaded in uniform shear. https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01 http://purl.org/dc/terms/type mathematical-law https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01 http://www.w3.org/1999/02/22-rdf-syntax-ns#type https://w3id.org/delphi/ontology/Claim https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01 http://www.w3.org/2000/01/rdf-schema#comment Notation basis: The bound is stated in the abstract; its derivation (balance of elastic energy stored in the strand against H-bond energy, giving a critical strand length) is in the full text, not vendored. https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01 http://www.w3.org/2000/01/rdf-schema#label At most three to four hydrogen bonds break together, whatever the assembly size https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01 http://www.w3.org/2004/02/skos/core#notation b_{\mathrm{rupture}} \le 3\text{–}4 \quad \text{for any } N \ge b \text{ H-bonds under uniform shear} https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01 https://w3id.org/delphi/ontology/context Sinan Keten et al., “Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale”, Nano Letters 8, 743-748 (2008), doi:10.1021/nl0731670; Abstract. Scope: Beta-sheet H-bond assemblies under shear, in theory and full-atomistic MD in explicit solvent https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/provenance https://doi.org/10.1021/nl0731670 http://purl.org/dc/terms/bibliographicCitation Sinan Keten, Markus J. Buehler. Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale. Nano Letters 8, 743-748 (2008). doi:10.1021/nl0731670 https://doi.org/10.1021/nl0731670 http://purl.org/dc/terms/creator Sinan Keten, Markus J. 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Checked by build/check.py. https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/quote http://www.w3.org/ns/prov#hadPrimarySource https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/quote http://www.w3.org/ns/prov#wasQuotedFrom https://doi.org/10.1021/nl0731670 https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/quote https://schema.org/text We discover that the rupture strength of H-bond assemblies is governed by geometric confinement effects, suggesting that clusters of at most 3-4 H-bonds break concurrently, even under uniform shear loading of a much larger number of H-bonds. https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/sourceChecksum http://spdx.org/rdf/terms#algorithm http://spdx.org/rdf/terms#checksumAlgorithm_sha256 https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/sourceChecksum http://spdx.org/rdf/terms#checksumValue 880dc02fe6911c5cdb1ab49189a7e6b0f6dc782017ec700c7a498afd4193e722 https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/sourceChecksum http://www.w3.org/2000/01/rdf-schema#comment Checksum of the vendored text file inputs/2008-hbond-confinement.abstract.txt, not of the publisher's copy. https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json http://spdx.org/rdf/terms#checksum https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/sourceChecksum https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json http://www.w3.org/1999/02/22-rdf-syntax-ns#type http://www.w3.org/ns/prov#Entity https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json http://www.w3.org/2000/01/rdf-schema#label Abstract of Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale, as read https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json https://schema.org/about https://doi.org/10.1021/nl0731670 https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/pubinfo https://w3id.org/delphi/resource/domain/buehler-protein-materials http://www.w3.org/2000/01/rdf-schema#label buehler-protein-materials https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://purl.org/dc/terms/created 2026-11-08T04:38:11.893Z https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://purl.org/dc/terms/creator https://orcid.org/0009-0007-4948-9192 https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://purl.org/dc/terms/license https://creativecommons.org/licenses/by/4.0/ https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://purl.org/nanopub/x/hasNanopubType https://w3id.org/delphi/ontology/Claim https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://purl.org/nanopub/x/introduces https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-01 https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk http://www.w3.org/2000/01/rdf-schema#label Sinan Keten et al. 2008 claim: At most three to four hydrogen bonds break together, whatever the assembly size https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk https://w3id.org/delphi/ontology/domain https://w3id.org/delphi/resource/domain/buehler-protein-materials https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/sig http://purl.org/nanopub/x/hasAlgorithm RSA https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/sig http://purl.org/nanopub/x/hasPublicKey MIIBIjANBgkqhkiG9w0BAQEFAAOCAQ8AMIIBCgKCAQEAyFHtPB6p0mCjDozxlOY9CmO3nBm7Te3jFbXyLmM+G1tGe47Da0jYIbhkl9Oo1ZjxmCa3LCwlEqK8gj6hEIcL4ahW30JXh9HycfKVk1bugkzMEV15tJdTzAU3sGMFnbNsn43xY2LFLy45tApkRm5byEiM7oRRrooIdwoQKnP4Wzq/bfAoJ9qvW+MGkelyOTd1jbSt+KfmT7xKmDfWzAHddUlWwMX2QJOLxDaffOteTop6ZRgPiNmPJKA/S62Gac9XtSYT3oDkZ6/nr5cxxNLpOyxTf5FPISiCe11xYO/unYjY+mwnOfA8yhJIyx1l0O9I0vpOpn+E5TvyHJV+oSTrvwIDAQAB https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/sig http://purl.org/nanopub/x/hasSignature XASB771nVEK/qy8id2Iy3HOtjkwNzGkjPJRsUArzNKMxcEPmruo/nFRJ/kMHDK3GhXxuk1kLl7MNJ7REAlK8woGdpaRK7prQjOX74P66PBaJZyW/iHxWepnkWpS6HbdRpeRbWeNR/EdVpybLnBHVlPGpqxHJhH18oejai06HqvlmAhOHZ0fQbOHS9up/UmzTytyI5u9plM0nvUnfzLnNv8GnMvoittUolC+s/ShLj2fu4nnUFvW3flY0teDyuu2SVGMNUjRFiAkXXwGmMkAbq0gyg2mYrgwe/vAR4kch7+A1Vt8K8L2kFdv9lP4KbJSUTLexH4Q1WJ6BhBJkFsZPYQ== https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/sig http://purl.org/nanopub/x/hasSignatureTarget https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk https://w3id.org/np/RATsvMjloIQfXxucYwweolDSkK5hJ7jZvMZR93jloO4lk/sig http://purl.org/nanopub/x/signedBy https://orcid.org/0009-0007-4948-9192