@prefix this: <https://w3id.org/np/RAztTt-XS2mpHBxN9FAaY8SI9HEAf_JEHl_0tLsuVnjAA> .
@prefix sub: <https://w3id.org/np/RAztTt-XS2mpHBxN9FAaY8SI9HEAf_JEHl_0tLsuVnjAA/> .
@prefix np: <http://www.nanopub.org/nschema#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix npx: <http://purl.org/nanopub/x/> .
@prefix dc: <http://purl.org/dc/terms/> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

sub:Head {
  this: a np:Nanopublication;
    np:hasAssertion sub:assertion;
    np:hasProvenance sub:provenance;
    np:hasPublicationInfo sub:pubinfo .
}

sub:assertion {
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    a prov:SoftwareAgent;
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  <https://w3id.org/delphi/resource/assessment/buehler-2007-tropocollagen-entropic-01--gpt>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:description "The low-strain and high-strain regimes can be distinguished in force-extension data, so part of the claim is testable with existing measurements. The molecular ordering of hydrogen-bond rupture, backbone deformation, and final fracture needs atomistic trajectories or specialized experiments and is not resolved by static structures or bulk collagen mechanics.";
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    <http://www.w3.org/2000/01/rdf-schema#comment> "Proposed test with existing data: Analyze single-tropocollagen force-extension data over the full extension range, fitting an entropic model at small strain and an energetic bond-deformation model at larger strain, while identifying hydrogen-bond loss, backbone deformation, and fracture where molecularly resolved data permit. Support requires the ordered crossover and failure sequence; absence or reversed ordering refutes it.";
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gpt-5.6-sol-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0";
    <https://w3id.org/delphi/ontology/evidenceAgainst> "Available structures and mechanical measurements may concern fibrils or short collagen-like peptides rather than the stated molecule.",
      "Force-extension curves do not directly identify hydrogen-bond versus covalent-bond deformation.",
      "Isolating and pulling a full-length single tropocollagen molecule is experimentally difficult.";
    <https://w3id.org/delphi/ontology/hasConfidence> "0.69"^^xsd:double;
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    <https://w3id.org/delphi/ontology/hasVerdict> "partially-resolvable" .
  
  <https://w3id.org/delphi/resource/assessment/buehler-2007-tropocollagen-entropic-01--gpt--analysis-feasibility>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gpt-5.6-sol-medium>;
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  <https://w3id.org/delphi/resource/assessment/buehler-2007-tropocollagen-entropic-01--gpt--data-existence>
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    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-data-existence>;
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gpt-5.6-sol-medium>;
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  <https://w3id.org/delphi/resource/assessment/buehler-2007-tropocollagen-entropic-01--gpt--discriminating-power>
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gpt-5.6-sol-medium>;
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    <https://w3id.org/delphi/ontology/hasScore> "0.6"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/buehler-2007-tropocollagen-entropic-01--gpt--operationalizability>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
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    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-operationalizability>;
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gpt-5.6-sol-medium>;
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  <https://w3id.org/delphi/resource/claim/buehler-2007-tropocollagen-entropic-01> <https://w3id.org/delphi/ontology/hasAssessment>
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      <https://w3id.org/delphi/resource/assessment/buehler-2007-tropocollagen-entropic-01--gpt--operationalizability> .
  
  <https://w3id.org/delphi/resource/evidence/buehler-2007-tropocollagen-entropic-01--gpt--dataset-1>
    a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "repository to locate public single-molecule mechanics data and study supplements";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: BioStudies";
    prov:wasDerivedFrom <https://www.ebi.ac.uk/biostudies/> .
  
  <https://w3id.org/delphi/resource/evidence/buehler-2007-tropocollagen-entropic-01--gpt--dataset-2>
    a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "experimental collagen structures that constrain molecular geometry but do not provide tensile trajectories";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: RCSB Protein Data Bank";
    prov:wasDerivedFrom <https://www.rcsb.org/> .
  
  <https://w3id.org/delphi/resource/model/gpt-5.6-sol-medium> a <https://w3id.org/delphi/ontology/LanguageModel>;
    dc:identifier "gpt-5.6-sol-medium";
    <http://www.w3.org/2000/01/rdf-schema#label> "GPT-5.6 Sol" .
}

sub:provenance {
  sub:assertion prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gpt-5.6-sol-medium>;
    prov:wasDerivedFrom <https://github.com/fractastical/delphisci/blob/67fe5b156cfeca15a2ded33e0face4177d03101c/claim-sources/buehler-protein-materials/assessment/raw/gpt/batch-1.json>,
      <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    prov:wasGeneratedBy sub:assessment .
  
  sub:assessment a prov:Activity;
    prov:qualifiedAssociation sub:assessmentPlan;
    prov:wasAssociatedWith <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gpt-5.6-sol-medium> .
  
  sub:assessmentPlan prov:hadPlan <https://github.com/fractastical/delphisci/blob/67fe5b156cfeca15a2ded33e0face4177d03101c/claim-sources/buehler-protein-materials/README.md> .
}

sub:pubinfo {
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      "buehler-protein-materials" .
  
  this: dc:created "2026-11-08T04:48:50.317Z"^^xsd:dateTime;
    dc:creator <https://orcid.org/0009-0007-4948-9192>;
    dc:license <https://creativecommons.org/licenses/by/4.0/>;
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    <https://w3id.org/delphi/ontology/domain> <https://w3id.org/delphi/resource/domain/buehler-protein-materials> .
  
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