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https://w3id.org/np/RAhMORtQhs7CM10AbC3L4i4jd-a2T3eV__XdRrCtqPwrc

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Content

@prefix this: <https://w3id.org/np/RAhMORtQhs7CM10AbC3L4i4jd-a2T3eV__XdRrCtqPwrc> .
@prefix sub: <https://w3id.org/np/RAhMORtQhs7CM10AbC3L4i4jd-a2T3eV__XdRrCtqPwrc/> .
@prefix np: <http://www.nanopub.org/nschema#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix npx: <http://purl.org/nanopub/x/> .
@prefix dc: <http://purl.org/dc/terms/> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

sub:Head {
  this: a np:Nanopublication;
    np:hasAssertion sub:assertion;
    np:hasProvenance sub:provenance;
    np:hasPublicationInfo sub:pubinfo .
}

sub:assertion {
  <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>
    a prov:SoftwareAgent;
    <http://www.w3.org/2000/01/rdf-schema#label> "delphisci dataset-resolvability assessor (Gemini 4 Argon)";
    prov:actedOnBehalfOf <https://orcid.org/0009-0007-4948-9192>;
    <https://w3id.org/delphi/ontology/usesModel> <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> .
  
  <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini> a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:description "The Curies' claim links macroscopic pyroelectricity and piezoelectricity directly to crystal point-group symmetry. This can be tested immediately against the Materials Project's piezoelectric tensor database (thousands of structures) and symmetry tensor tables on the Bilbao Crystallographic Server: true pyroelectricity requires one of the 10 polar point groups, whereas piezoelectricity occurs across 20 non-centrosymmetric point groups (including 10 non-polar classes such as 32 in quartz and -43m in sphalerite that are piezoelectric but not pyroelectric).";
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    <http://www.w3.org/2000/01/rdf-schema#comment> "Proposed test with existing data: Group crystalline materials by their 32 crystallographic point groups and test whether nonzero piezoelectric tensors (d_{ijk}) and pyroelectric vectors (p_i) occur exclusively in the 10 polar point groups ('hemihedral with inclined faces') or across the broader set of 20 non-centrosymmetric point groups. Confirm the pyroelectric restriction if spontaneous polarization is confined to the 10 polar classes, and refute the strict equivalence of pyroelectric and piezoelectric crystal classes by checking non-polar non-centrosymmetric crystals (such as α-quartz in point group 32 or sphalerite in -43m) that exhibit strong piezoelectricity without pyroelectricity.";
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0";
    <https://w3id.org/delphi/ontology/evidenceAgainst> "Curie's 1880 terminology 'hémièdres à faces inclinées' grouped non-centrosymmetric crystals tested in Note I (which included quartz, point group 32, and sphalerite, point group -43m) before Voigt (1894) formalized the exact distinction between the 10 polar pyroelectric classes and the 20 piezoelectric classes";
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    <https://w3id.org/delphi/ontology/hasEvidence> <https://w3id.org/delphi/resource/evidence/curie1880-01--gemini--dataset-1>,
      <https://w3id.org/delphi/resource/evidence/curie1880-01--gemini--dataset-2>;
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    <https://w3id.org/delphi/ontology/hasVerdict> "resolvable-now" .
  
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
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    <https://w3id.org/delphi/ontology/hasScore> "0.95"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini--operationalizability>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-operationalizability>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Operationalizability of curie1880-01 by Gemini 4 Argon: 0.95";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
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      <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini>, <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini--analysis-feasibility>,
      <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini--data-adequacy>,
      <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini--data-existence>,
      <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini--discriminating-power>,
      <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini--operationalizability> .
  
  <https://w3id.org/delphi/resource/evidence/curie1880-01--gemini--dataset-1> a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Provides computed piezoelectric tensors for thousands of crystalline materials indexed by space group and point group.";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: Materials Project";
    prov:wasDerivedFrom <https://materialsproject.org/> .
  
  <https://w3id.org/delphi/resource/evidence/curie1880-01--gemini--dataset-2> a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Supplies point-group and space-group assignments for reference piezoelectric and pyroelectric minerals (quartz, tourmaline, sphalerite, topaz, Rochelle salt).";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: Crystallography Open Database (COD)";
    prov:wasDerivedFrom <https://www.crystallography.net/cod/> .
  
  <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> a <https://w3id.org/delphi/ontology/LanguageModel>;
    dc:identifier "gemini-4-argon-medium";
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon" .
}

sub:provenance {
  sub:assertion prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    prov:wasDerivedFrom <https://github.com/fractastical/delphisci/blob/5241dc54170fa807613109d52197d32342021641/claim-sources/crystals-and-form/assessment/raw/gemini/batch-2.json>,
      <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    prov:wasGeneratedBy sub:assessment .
  
  sub:assessment a prov:Activity;
    prov:qualifiedAssociation sub:assessmentPlan;
    prov:wasAssociatedWith <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium> .
  
  sub:assessmentPlan prov:hadPlan <https://github.com/fractastical/delphisci/blob/5241dc54170fa807613109d52197d32342021641/claim-sources/crystals-and-form/README.md> .
}

sub:pubinfo {
  <https://w3id.org/delphi/resource/domain/crystals-and-form> <http://www.w3.org/2000/01/rdf-schema#label>
      "crystals-and-form" .
  
  this: dc:created "2026-11-07T03:18:24.087Z"^^xsd:dateTime;
    dc:creator <https://orcid.org/0009-0007-4948-9192>;
    dc:license <https://creativecommons.org/licenses/by/4.0/>;
    npx:hasNanopubType <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    npx:introduces <https://w3id.org/delphi/resource/assessment/curie1880-01--gemini>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon on curie1880-01: resolvable-now, resolvability 0.94";
    <https://w3id.org/delphi/ontology/domain> <https://w3id.org/delphi/resource/domain/crystals-and-form> .
  
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