@prefix this: <https://w3id.org/np/RAbJcshVY5hlrCVCgxYnWzcoOfpP0fHPywdcyOc_4J8Ec> .
@prefix sub: <https://w3id.org/np/RAbJcshVY5hlrCVCgxYnWzcoOfpP0fHPywdcyOc_4J8Ec/> .
@prefix np: <http://www.nanopub.org/nschema#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix npx: <http://purl.org/nanopub/x/> .
@prefix dc: <http://purl.org/dc/terms/> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

sub:Head {
  this: a np:Nanopublication;
    np:hasAssertion sub:assertion;
    np:hasProvenance sub:provenance;
    np:hasPublicationInfo sub:pubinfo .
}

sub:assertion {
  <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>
    a prov:SoftwareAgent;
    <http://www.w3.org/2000/01/rdf-schema#label> "delphisci dataset-resolvability assessor (Gemini 4 Argon)";
    prov:actedOnBehalfOf <https://orcid.org/0009-0007-4948-9192>;
    <https://w3id.org/delphi/ontology/usesModel> <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini> a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:description "While the algebraic relation between unit-cell volume, density, and atomic mass is a mathematical identity given the structural assignment Z = 4, its empirical prediction—that density and the hydrogen atom mass yield absolute lattice spacings in centimetres matching independent X-ray wavelength measurements—is immediately testable and confirmed across alkali halides in COD and NIST tables.";
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    <http://www.w3.org/2000/01/rdf-schema#comment> "Proposed test with existing data: For rock-salt-type alkali halides (NaCl, KCl, KBr, KI) with Z = 4 formula units per conventional FCC unit cell, compute the lattice constant in centimetres from macroscopic density rho, molar mass M, and the atomic mass unit m_u via a = (4 * M * m_u / rho)^(1/3), and compare against independent absolute X-ray interferometric and diffraction lattice constants.";
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon on bragg1913s-05: resolvable-now, resolvability 0.92";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0";
    <https://w3id.org/delphi/ontology/evidenceAgainst> "Real crystals contain point defects (vacancies) that introduce a ~10^-4 difference between macroscopic pycnometric density and X-ray density",
      "The formula a = (Z*M*m_u/rho)^(1/3) is a mathematical identity once the unit-cell stoichiometry Z is fixed; its empirical content lies in the agreement between density-derived lattice spacings and absolute X-ray wavelength measurements";
    <https://w3id.org/delphi/ontology/hasConfidence> "0.9"^^xsd:double;
    <https://w3id.org/delphi/ontology/hasEvidence> <https://w3id.org/delphi/resource/evidence/bragg1913s-05--gemini--dataset-1>,
      <https://w3id.org/delphi/resource/evidence/bragg1913s-05--gemini--dataset-2>;
    <https://w3id.org/delphi/ontology/hasScore> "0.92"^^xsd:double;
    <https://w3id.org/delphi/ontology/hasVerdict> "resolvable-now" .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--analysis-feasibility>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-analysis-feasibility>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Analysis feasibility of bragg1913s-05 by Gemini 4 Argon: 0.95";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/analysis-feasibility";
    <https://w3id.org/delphi/ontology/hasScore> "0.95"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--data-adequacy>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-data-adequacy>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Data adequacy of bragg1913s-05 by Gemini 4 Argon: 0.95";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/data-adequacy";
    <https://w3id.org/delphi/ontology/hasScore> "0.95"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--data-existence>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-data-existence>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Data existence of bragg1913s-05 by Gemini 4 Argon: 0.95";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/data-existence";
    <https://w3id.org/delphi/ontology/hasScore> "0.95"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--discriminating-power>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-discriminating-power>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Discriminating power of bragg1913s-05 by Gemini 4 Argon: 0.9";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/discriminating-power";
    <https://w3id.org/delphi/ontology/hasScore> "0.9"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--operationalizability>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-operationalizability>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Operationalizability of bragg1913s-05 by Gemini 4 Argon: 0.85";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/operationalizability";
    <https://w3id.org/delphi/ontology/hasScore> "0.85"^^xsd:double .
  
  <https://w3id.org/delphi/resource/claim/bragg1913s-05> <https://w3id.org/delphi/ontology/hasAssessment>
      <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini>, <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--analysis-feasibility>,
      <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--data-adequacy>,
      <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--data-existence>,
      <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--discriminating-power>,
      <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini--operationalizability> .
  
  <https://w3id.org/delphi/resource/evidence/bragg1913s-05--gemini--dataset-1> a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Supplies independently measured X-ray diffraction lattice parameters and densities for alkali halides.";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: Crystallography Open Database (COD)";
    prov:wasDerivedFrom <https://www.crystallography.net/cod/> .
  
  <https://w3id.org/delphi/resource/evidence/bragg1913s-05--gemini--dataset-2> a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Provides CODATA fundamental physical constants (atomic mass constant m_u, Avogadro constant) and reference crystal densities.";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: NIST Standard Reference Data";
    prov:wasDerivedFrom <https://www.nist.gov/srd> .
  
  <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> a <https://w3id.org/delphi/ontology/LanguageModel>;
    dc:identifier "gemini-4-argon-medium";
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon" .
}

sub:provenance {
  sub:assertion prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    prov:wasDerivedFrom <https://github.com/fractastical/delphisci/blob/5241dc54170fa807613109d52197d32342021641/claim-sources/crystals-and-form/assessment/raw/gemini/batch-4.json>,
      <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    prov:wasGeneratedBy sub:assessment .
  
  sub:assessment a prov:Activity;
    prov:qualifiedAssociation sub:assessmentPlan;
    prov:wasAssociatedWith <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium> .
  
  sub:assessmentPlan prov:hadPlan <https://github.com/fractastical/delphisci/blob/5241dc54170fa807613109d52197d32342021641/claim-sources/crystals-and-form/README.md> .
}

sub:pubinfo {
  <https://w3id.org/delphi/resource/domain/crystals-and-form> <http://www.w3.org/2000/01/rdf-schema#label>
      "crystals-and-form" .
  
  this: dc:created "2026-11-07T03:18:24.087Z"^^xsd:dateTime;
    dc:creator <https://orcid.org/0009-0007-4948-9192>;
    dc:license <https://creativecommons.org/licenses/by/4.0/>;
    npx:hasNanopubType <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    npx:introduces <https://w3id.org/delphi/resource/assessment/bragg1913s-05--gemini>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon on bragg1913s-05: resolvable-now, resolvability 0.92";
    <https://w3id.org/delphi/ontology/domain> <https://w3id.org/delphi/resource/domain/crystals-and-form> .
  
  sub:sig npx:hasAlgorithm "RSA";
    npx:hasPublicKey "MIIBIjANBgkqhkiG9w0BAQEFAAOCAQ8AMIIBCgKCAQEAyFHtPB6p0mCjDozxlOY9CmO3nBm7Te3jFbXyLmM+G1tGe47Da0jYIbhkl9Oo1ZjxmCa3LCwlEqK8gj6hEIcL4ahW30JXh9HycfKVk1bugkzMEV15tJdTzAU3sGMFnbNsn43xY2LFLy45tApkRm5byEiM7oRRrooIdwoQKnP4Wzq/bfAoJ9qvW+MGkelyOTd1jbSt+KfmT7xKmDfWzAHddUlWwMX2QJOLxDaffOteTop6ZRgPiNmPJKA/S62Gac9XtSYT3oDkZ6/nr5cxxNLpOyxTf5FPISiCe11xYO/unYjY+mwnOfA8yhJIyx1l0O9I0vpOpn+E5TvyHJV+oSTrvwIDAQAB";
    npx:hasSignature "ldUoQ+HHUjG6fkAabCHBn7OdM9ETs8XKsAVy8E+PdocueG8+EuZkqFN0ePs2pfv7VlKdGFQqSdKplzxywpGeDsnF828erSGRNckGx76FTJ9zDgXSNP5YPfe40AZEF1tJSK7mQeGKHR+qwDkGYXRkjMBsNFwGvW1VSWEeeGqlXsc7PKk5xuV3yf5iBz/x5u/nM1ZIS5EXRYwxBLMT7F5UX/gJDHLEwLQX2ipTHzlLPC2axkYPCLWN6QnsuT3UvVEi6f53K3njP4m+XAsXaEMU+daJ6YPWopAcsr5dzHH76tFjBVyz51B3UOWB3rvWOZPjj5CbQLXslTGBM/ZUHXgZMA==";
    npx:hasSignatureTarget this:;
    npx:signedBy <https://orcid.org/0009-0007-4948-9192> .
}