@prefix this: <https://w3id.org/np/RAUHp588TPp98Mk_gHWP-9Q6qRMFRc7FkLixEAcJc32Bw> .
@prefix sub: <https://w3id.org/np/RAUHp588TPp98Mk_gHWP-9Q6qRMFRc7FkLixEAcJc32Bw/> .
@prefix np: <http://www.nanopub.org/nschema#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix npx: <http://purl.org/nanopub/x/> .
@prefix dc: <http://purl.org/dc/terms/> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

sub:Head {
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    np:hasAssertion sub:assertion;
    np:hasProvenance sub:provenance;
    np:hasPublicationInfo sub:pubinfo .
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sub:assertion {
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    dc:description "Bragg's law is both a geometric wave-interference derivation and the foundational empirical relation of X-ray diffraction. Using experimental powder diffraction patterns in RRUFF and NIST Standard Reference Materials with certified wavelengths and lattice parameters, the relation n*lambda = 2*d*sin(theta) can be tested directly across thousands of reflections to sub-arcsecond precision.";
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    <http://www.w3.org/2000/01/rdf-schema#comment> "Proposed test with existing data: For crystals with independently known interplanar spacings d(hkl) illuminated by monochromatic X-rays of known wavelength lambda, measure the glancing angles theta of diffraction peaks across reflection orders n and test whether n*lambda / (2*d*sin(theta)) = 1 within experimental precision (accounting for the ~10^-5 X-ray refractive-index correction).";
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0";
    <https://w3id.org/delphi/ontology/evidenceAgainst> "As a purely geometric wave-interference condition on periodic planes, the equation is a mathematical theorem; empirically, dynamical diffraction adds a tiny refractive-index correction (Darwin-Prins shift of order 10^-5) at low angles";
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    <https://w3id.org/delphi/ontology/hasVerdict> "resolvable-now" .
  
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
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    dc:description "Provides hundreds of thousands of X-ray diffraction crystal structures and indexed reflection geometries.";
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    prov:wasDerivedFrom <https://www.crystallography.net/cod/> .
  
  <https://w3id.org/delphi/resource/evidence/bragg1913s-01--gemini--dataset-2> a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Supplies experimental powder X-ray diffraction patterns (2-theta peak positions at known Cu K-alpha wavelength) paired with unit-cell refinements.";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: RRUFF Project";
    prov:wasDerivedFrom <https://rruff.info/> .
  
  <https://w3id.org/delphi/resource/evidence/bragg1913s-01--gemini--dataset-3> a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Provides certified lattice spacings and diffraction peak angles for X-ray diffraction line-position standards (e.g., Si SRM 640, LaB6 SRM 660).";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: NIST Standard Reference Data";
    prov:wasDerivedFrom <https://www.nist.gov/srd> .
  
  <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> a <https://w3id.org/delphi/ontology/LanguageModel>;
    dc:identifier "gemini-4-argon-medium";
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon" .
}

sub:provenance {
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    prov:wasDerivedFrom <https://github.com/fractastical/delphisci/blob/5241dc54170fa807613109d52197d32342021641/claim-sources/crystals-and-form/assessment/raw/gemini/batch-4.json>,
      <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    prov:wasGeneratedBy sub:assessment .
  
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    prov:qualifiedAssociation sub:assessmentPlan;
    prov:wasAssociatedWith <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium> .
  
  sub:assessmentPlan prov:hadPlan <https://github.com/fractastical/delphisci/blob/5241dc54170fa807613109d52197d32342021641/claim-sources/crystals-and-form/README.md> .
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sub:pubinfo {
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      "crystals-and-form" .
  
  this: dc:created "2026-11-07T03:18:24.087Z"^^xsd:dateTime;
    dc:creator <https://orcid.org/0009-0007-4948-9192>;
    dc:license <https://creativecommons.org/licenses/by/4.0/>;
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    npx:introduces <https://w3id.org/delphi/resource/assessment/bragg1913s-01--gemini>;
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