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Nanoconfinement enhances the nanocrystals' properties by combining uniform shear deformation, which uses hydrogen bonds most efficiently, with dissipative molecular stick–slip deformation.
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Sinan Keten et al., “Nanoconfinement controls stiffness, strength and mechanical toughness of β-sheet crystals in silk”, Nature Materials 9, 359-367 (2010), doi:10.1038/nmat2704; Abstract. Scope: Silk beta-sheet nanocrystals in MD pull-out simulations
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Sinan Keten, Zhiping Xu, Britni Ihle, Markus J. Buehler. Nanoconfinement controls stiffness, strength and mechanical toughness of β-sheet crystals in silk. Nature Materials 9, 359-367 (2010). doi:10.1038/nmat2704
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Nanoconfinement controls stiffness, strength and mechanical toughness of β-sheet crystals in silk
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We illustrate that through nanoconfinement, a combination of uniform shear deformation that makes most efficient use of hydrogen bonds and the emergence of dissipative molecular stick-slip deformation leads to significantly enhanced mechanical properties.
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Abstract of Nanoconfinement controls stiffness, strength and mechanical toughness of β-sheet crystals in silk, as read
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