@prefix this: <https://w3id.org/np/RARCmsXyXvoG6sfWUywcUdh9oJcXlTxGwID9Q-vii4tQs> .
@prefix sub: <https://w3id.org/np/RARCmsXyXvoG6sfWUywcUdh9oJcXlTxGwID9Q-vii4tQs/> .
@prefix np: <http://www.nanopub.org/nschema#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix npx: <http://purl.org/nanopub/x/> .
@prefix dc: <http://purl.org/dc/terms/> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

sub:Head {
  this: a np:Nanopublication;
    np:hasAssertion sub:assertion;
    np:hasProvenance sub:provenance;
    np:hasPublicationInfo sub:pubinfo .
}

sub:assertion {
  <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>
    a prov:SoftwareAgent;
    <http://www.w3.org/2000/01/rdf-schema#label> "delphisci dataset-resolvability assessor (Gemini 4 Argon)";
    prov:actedOnBehalfOf <https://orcid.org/0009-0007-4948-9192>;
    <https://w3id.org/delphi/ontology/usesModel> <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> .
  
  <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:description "The mathematical derivation extending Bell's theory is directly checkable, and its empirical content—that protein domain strength follows from H-bond cluster hierarchy—can be tested against published AFM/optical-tweezers force spectra and steered MD data. However, experimental force-velocity data are fragmented across the literature, and the abstract does not state the full closed-form multi-hierarchy coupling, leaving parameter identifiability only partially constrained.";
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    <http://www.w3.org/2000/01/rdf-schema#comment> "Proposed test with existing data: Fit the hierarchical Bell expression F(v) with cluster-size-scaled barrier E_b and transition-state distance x_b to published dynamic force spectroscopy and steered MD unfolding force-velocity curves across diverse protein domains, testing whether architecture-derived b values predict rupture forces without free fitting of x_b.";
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon on buehler-2007-hierarchies-03: partially-resolvable, resolvability 0.65";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0";
    <https://w3id.org/delphi/ontology/evidenceAgainst> "Because single-bond energy E_1 and distance x_1 depend on local microenvironment and solvent exposure, fitting b can become degenerate with effective bond parameters.",
      "Experimental single-molecule force spectroscopy datasets across multiple pulling velocities are scattered across individual papers rather than unified in one open repository.";
    <https://w3id.org/delphi/ontology/hasConfidence> "0.75"^^xsd:double;
    <https://w3id.org/delphi/ontology/hasEvidence> <https://w3id.org/delphi/resource/evidence/buehler-2007-hierarchies-03--gemini--dataset-1>;
    <https://w3id.org/delphi/ontology/hasScore> "0.653"^^xsd:double;
    <https://w3id.org/delphi/ontology/hasVerdict> "partially-resolvable" .
  
  <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--analysis-feasibility>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-analysis-feasibility>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Analysis feasibility of buehler-2007-hierarchies-03 by Gemini 4 Argon: 0.75";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/analysis-feasibility";
    <https://w3id.org/delphi/ontology/hasScore> "0.75"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--data-adequacy>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-data-adequacy>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Data adequacy of buehler-2007-hierarchies-03 by Gemini 4 Argon: 0.55";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/data-adequacy";
    <https://w3id.org/delphi/ontology/hasScore> "0.55"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--data-existence>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-data-existence>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Data existence of buehler-2007-hierarchies-03 by Gemini 4 Argon: 0.6";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/data-existence";
    <https://w3id.org/delphi/ontology/hasScore> "0.6"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--discriminating-power>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-discriminating-power>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Discriminating power of buehler-2007-hierarchies-03 by Gemini 4 Argon: 0.65";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/discriminating-power";
    <https://w3id.org/delphi/ontology/hasScore> "0.65"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--operationalizability>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-operationalizability>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Operationalizability of buehler-2007-hierarchies-03 by Gemini 4 Argon: 0.75";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/operationalizability";
    <https://w3id.org/delphi/ontology/hasScore> "0.75"^^xsd:double .
  
  <https://w3id.org/delphi/resource/claim/buehler-2007-hierarchies-03> <https://w3id.org/delphi/ontology/hasAssessment>
      <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini>,
      <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--analysis-feasibility>,
      <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--data-adequacy>,
      <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--data-existence>,
      <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--discriminating-power>,
      <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini--operationalizability> .
  
  <https://w3id.org/delphi/resource/evidence/buehler-2007-hierarchies-03--gemini--dataset-1>
    a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Three-dimensional protein structures from which H-bond topology and parallel cluster sizes b can be extracted";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: RCSB Protein Data Bank";
    prov:wasDerivedFrom <https://www.rcsb.org/> .
  
  <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> a <https://w3id.org/delphi/ontology/LanguageModel>;
    dc:identifier "gemini-4-argon-medium";
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon" .
}

sub:provenance {
  sub:assertion prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    prov:wasDerivedFrom <https://github.com/fractastical/delphisci/blob/67fe5b156cfeca15a2ded33e0face4177d03101c/claim-sources/buehler-protein-materials/assessment/raw/gemini/batch-1.json>,
      <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    prov:wasGeneratedBy sub:assessment .
  
  sub:assessment a prov:Activity;
    prov:qualifiedAssociation sub:assessmentPlan;
    prov:wasAssociatedWith <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium> .
  
  sub:assessmentPlan prov:hadPlan <https://github.com/fractastical/delphisci/blob/67fe5b156cfeca15a2ded33e0face4177d03101c/claim-sources/buehler-protein-materials/README.md> .
}

sub:pubinfo {
  <https://w3id.org/delphi/resource/domain/buehler-protein-materials> <http://www.w3.org/2000/01/rdf-schema#label>
      "buehler-protein-materials" .
  
  this: dc:created "2026-11-08T04:48:50.317Z"^^xsd:dateTime;
    dc:creator <https://orcid.org/0009-0007-4948-9192>;
    dc:license <https://creativecommons.org/licenses/by/4.0/>;
    npx:hasNanopubType <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    npx:introduces <https://w3id.org/delphi/resource/assessment/buehler-2007-hierarchies-03--gemini>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon on buehler-2007-hierarchies-03: partially-resolvable, resolvability 0.65";
    <https://w3id.org/delphi/ontology/domain> <https://w3id.org/delphi/resource/domain/buehler-protein-materials> .
  
  sub:sig npx:hasAlgorithm "RSA";
    npx:hasPublicKey "MIIBIjANBgkqhkiG9w0BAQEFAAOCAQ8AMIIBCgKCAQEAyFHtPB6p0mCjDozxlOY9CmO3nBm7Te3jFbXyLmM+G1tGe47Da0jYIbhkl9Oo1ZjxmCa3LCwlEqK8gj6hEIcL4ahW30JXh9HycfKVk1bugkzMEV15tJdTzAU3sGMFnbNsn43xY2LFLy45tApkRm5byEiM7oRRrooIdwoQKnP4Wzq/bfAoJ9qvW+MGkelyOTd1jbSt+KfmT7xKmDfWzAHddUlWwMX2QJOLxDaffOteTop6ZRgPiNmPJKA/S62Gac9XtSYT3oDkZ6/nr5cxxNLpOyxTf5FPISiCe11xYO/unYjY+mwnOfA8yhJIyx1l0O9I0vpOpn+E5TvyHJV+oSTrvwIDAQAB";
    npx:hasSignature "MZgnvI646KnxhW87ZM7Sw+7v80c4BsaKTct1UsX8rk8BDetdpD+572Zq0q8KDHWhHooiBqhiPQUQQOILARGMCYo7MIU0BeU9ojRaQSncypKZzbwJJ5EHvseB2/AX5VTDGG60sXvHZv7mI/BDf5dYgke7zxlusMqQugXerw7M1DUtDUirysMOqcTwKBCyfUKehcLTPmYnG8CNfHO3umNmQKeYa/FCYQq3Hcb2pEK1AAs5M80P2lV3a6r63WD5xIFrGTwK0g0aoHTT9x2T/TxaQjzEQgp8RDRjYNtwoF+pfxK68ZD+EeBhTEPMqY0uNvtDujs2oeXqZy824rehGIKV4A==";
    npx:hasSignatureTarget this:;
    npx:signedBy <https://orcid.org/0009-0007-4948-9192> .
}