@prefix this: <https://w3id.org/np/RAIKUmHgZB1IGDAo9RF65N19EARxy5CfLLi8jWoenSXgQ> .
@prefix sub: <https://w3id.org/np/RAIKUmHgZB1IGDAo9RF65N19EARxy5CfLLi8jWoenSXgQ/> .
@prefix np: <http://www.nanopub.org/nschema#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix npx: <http://purl.org/nanopub/x/> .
@prefix dc: <http://purl.org/dc/terms/> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

sub:Head {
  this: a np:Nanopublication;
    np:hasAssertion sub:assertion;
    np:hasProvenance sub:provenance;
    np:hasPublicationInfo sub:pubinfo .
}

sub:assertion {
  <https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-03> a <https://w3id.org/delphi/ontology/Claim>;
    dc:description "Large, strong beta-sheet structures become possible by forming a nanocomposite of many small H-bond clusters, each at or below the critical size, which circumvents the strength limit of a single assembly.";
    dc:type "mechanism";
    <http://www.w3.org/2000/01/rdf-schema#label> "Nanocomposites of H-bond clusters overcome the intrinsic strength limit";
    <https://w3id.org/delphi/ontology/context> "Sinan Keten et al., “Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale”, Nano Letters 8, 743-748 (2008), doi:10.1021/nl0731670; Abstract. Scope: Beta-sheet-rich protein materials (silk, amyloid, muscle)" .
}

sub:provenance {
  <https://doi.org/10.1021/nl0731670> a <https://schema.org/CreativeWork>;
    dc:bibliographicCitation "Sinan Keten, Markus J. Buehler. Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale. Nano Letters 8, 743-748 (2008). doi:10.1021/nl0731670";
    dc:creator "Sinan Keten, Markus J. Buehler";
    dc:date "2008"^^xsd:gYear;
    dc:identifier "doi:10.1021/nl0731670", "pmid:18269263";
    dc:title "Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale" .
  
  <https://w3id.org/delphi/resource/agent/delphisci-buehler-protein-materials-extractor>
    a prov:SoftwareAgent;
    <http://www.w3.org/2000/01/rdf-schema#label> "delphisci buehler-protein-materials claim extractor";
    prov:actedOnBehalfOf <https://orcid.org/0009-0007-4948-9192>;
    <https://w3id.org/delphi/ontology/usesModel> <https://w3id.org/delphi/resource/model/claude-fable-5.1> .
  
  <https://w3id.org/delphi/resource/model/claude-fable-5.1> a <https://w3id.org/delphi/ontology/LanguageModel>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Claude Fable 5.1" .
  
  sub:assertion prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-buehler-protein-materials-extractor>;
    prov:wasDerivedFrom <https://doi.org/10.1021/nl0731670>, sub:quote;
    prov:wasGeneratedBy sub:extraction .
  
  sub:extraction a prov:Activity;
    prov:qualifiedAssociation sub:extractionPlan;
    prov:used <https://github.com/fractastical/delphisci/blob/b89a0890bee05ef18f8202387085854fac3ca776/claim-sources/buehler-protein-materials/inputs/sources.json>,
      <https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json>;
    prov:wasAssociatedWith <https://w3id.org/delphi/resource/agent/delphisci-buehler-protein-materials-extractor> .
  
  sub:extractionPlan prov:hadPlan <https://github.com/fractastical/delphisci/blob/b89a0890bee05ef18f8202387085854fac3ca776/claim-sources/buehler-protein-materials/build/generate.mjs> .
  
  sub:quote a prov:Entity;
    <http://www.w3.org/2000/01/rdf-schema#comment> "Quoted from the published abstract as returned by Europe PMC (2008-hbond-confinement.abstract.txt, sha256 880dc02fe6911c5cdb1ab49189a7e6b0f6dc782017ec700c7a498afd4193e722); the full text was not read (not in Europe PMC open-access subset). Checked by build/check.py.";
    prov:hadPrimarySource <https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json>;
    prov:wasQuotedFrom <https://doi.org/10.1021/nl0731670>;
    <https://schema.org/text> "Our finding explains how the intrinsic strength limitation of H-bonds can be overcome by the formation of a nanocomposite structure of H-bond clusters, thereby enabling the formation of larger and much stronger beta-sheet structures." .
  
  sub:sourceChecksum <http://spdx.org/rdf/terms#algorithm> <http://spdx.org/rdf/terms#checksumAlgorithm_sha256>;
    <http://spdx.org/rdf/terms#checksumValue> "880dc02fe6911c5cdb1ab49189a7e6b0f6dc782017ec700c7a498afd4193e722";
    <http://www.w3.org/2000/01/rdf-schema#comment> "Checksum of the vendored text file inputs/2008-hbond-confinement.abstract.txt, not of the publisher's copy." .
  
  <https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=DOI:10.1021/nl0731670&resultType=core&format=json>
    a prov:Entity;
    <http://spdx.org/rdf/terms#checksum> sub:sourceChecksum;
    <http://www.w3.org/2000/01/rdf-schema#label> "Abstract of Geometric Confinement Governs the Rupture Strength of H-bond Assemblies at a Critical Length Scale, as read";
    <https://schema.org/about> <https://doi.org/10.1021/nl0731670> .
}

sub:pubinfo {
  <https://w3id.org/delphi/resource/domain/buehler-protein-materials> <http://www.w3.org/2000/01/rdf-schema#label>
      "buehler-protein-materials" .
  
  this: dc:created "2026-11-08T04:38:11.893Z"^^xsd:dateTime;
    dc:creator <https://orcid.org/0009-0007-4948-9192>;
    dc:license <https://creativecommons.org/licenses/by/4.0/>;
    npx:hasNanopubType <https://w3id.org/delphi/ontology/Claim>;
    npx:introduces <https://w3id.org/delphi/resource/claim/buehler-2008-hbond-confinement-03>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Sinan Keten et al. 2008 claim: Nanocomposites of H-bond clusters overcome the intrinsic strength limit";
    <https://w3id.org/delphi/ontology/domain> <https://w3id.org/delphi/resource/domain/buehler-protein-materials> .
  
  sub:sig npx:hasAlgorithm "RSA";
    npx:hasPublicKey "MIIBIjANBgkqhkiG9w0BAQEFAAOCAQ8AMIIBCgKCAQEAyFHtPB6p0mCjDozxlOY9CmO3nBm7Te3jFbXyLmM+G1tGe47Da0jYIbhkl9Oo1ZjxmCa3LCwlEqK8gj6hEIcL4ahW30JXh9HycfKVk1bugkzMEV15tJdTzAU3sGMFnbNsn43xY2LFLy45tApkRm5byEiM7oRRrooIdwoQKnP4Wzq/bfAoJ9qvW+MGkelyOTd1jbSt+KfmT7xKmDfWzAHddUlWwMX2QJOLxDaffOteTop6ZRgPiNmPJKA/S62Gac9XtSYT3oDkZ6/nr5cxxNLpOyxTf5FPISiCe11xYO/unYjY+mwnOfA8yhJIyx1l0O9I0vpOpn+E5TvyHJV+oSTrvwIDAQAB";
    npx:hasSignature "IIni227pN1sXlcC7dekbT/+iNcdfltls42hH9iP22dsSA6S/Avm/fshHidnQPAhqg3vpEIoKc96Vyc9axf1B7CPB0POjgvnsgzPUilv/VegHjEzN0U5VWxvktTQPeYVu9XUgiacasS8XwD+rttud2CUoCJ6X0c9Bb/tjSn1wFj7O6k0Dk0R1OTF/k7YPL2TU71J7Af3fZ34K7Hy5dahAwZes85QGwMWKF2G28W5Xp69F1OstJZSA+HzH+wFuhc/DkbJF86aQrdSBy26JKp+qZZgorOV2qbTfNTIJzQctJzOIgGKmAxKsAA/6YafIZEtq5kDTZ/Ru/DJVLIACnUgE+w==";
    npx:hasSignatureTarget this:;
    npx:signedBy <https://orcid.org/0009-0007-4948-9192> .
}