@prefix this: <https://w3id.org/np/RABSH3ddNRCpEmwJZjnkL92vrbzlMQRP1kWIQhNxohZHk> .
@prefix sub: <https://w3id.org/np/RABSH3ddNRCpEmwJZjnkL92vrbzlMQRP1kWIQhNxohZHk/> .
@prefix np: <http://www.nanopub.org/nschema#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix npx: <http://purl.org/nanopub/x/> .
@prefix dc: <http://purl.org/dc/terms/> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

sub:Head {
  this: a np:Nanopublication;
    np:hasAssertion sub:assertion;
    np:hasProvenance sub:provenance;
    np:hasPublicationInfo sub:pubinfo .
}

sub:assertion {
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    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:description "Both halves of the claim are readily testable now: the analytical optimum of 3–4 parallel H-bonds per turn follows directly from evaluating the hierarchical Bell equations, and the empirical comparison to 3.6 H-bonds per turn in natural alpha-helices can be verified across hundreds of thousands of structures in the RCSB PDB using standard secondary-structure assignment tools.";
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    <http://www.w3.org/2000/01/rdf-schema#comment> "Proposed test with existing data: Evaluate the hierarchical Bell model's effective activation barrier and unfolding force as a function of parallel H-bonds per helical turn b to verify the predicted optimum at b in {3, 4}, and compute the empirical distribution of residues/H-bonds per turn across all alpha-helices in the PDB using DSSP.";
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    <https://w3id.org/delphi/ontology/evidenceAgainst> "The exact weighting between mechanical rupture force and thermal unfolding stability in the model's optimality criterion must be taken from the full derivation.";
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    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
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    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
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  <https://w3id.org/delphi/resource/claim/buehler-2007-hierarchies-04> <https://w3id.org/delphi/ontology/hasAssessment>
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    a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "High-resolution crystal and cryo-EM protein structures for measuring empirical helical periodicity and H-bonds per turn across the proteome";
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    prov:wasDerivedFrom <https://www.rcsb.org/> .
  
  <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> a <https://w3id.org/delphi/ontology/LanguageModel>;
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    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon" .
}

sub:provenance {
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    prov:wasDerivedFrom <https://github.com/fractastical/delphisci/blob/67fe5b156cfeca15a2ded33e0face4177d03101c/claim-sources/buehler-protein-materials/assessment/raw/gemini/batch-1.json>,
      <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    prov:wasGeneratedBy sub:assessment .
  
  sub:assessment a prov:Activity;
    prov:qualifiedAssociation sub:assessmentPlan;
    prov:wasAssociatedWith <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium> .
  
  sub:assessmentPlan prov:hadPlan <https://github.com/fractastical/delphisci/blob/67fe5b156cfeca15a2ded33e0face4177d03101c/claim-sources/buehler-protein-materials/README.md> .
}

sub:pubinfo {
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      "buehler-protein-materials" .
  
  this: dc:created "2026-11-08T04:48:50.317Z"^^xsd:dateTime;
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    dc:license <https://creativecommons.org/licenses/by/4.0/>;
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}