@prefix this: <https://w3id.org/np/RA3BEGI32cq4e5xOVI5cKCflT_nThT5Imx47higvo4jlA> .
@prefix sub: <https://w3id.org/np/RA3BEGI32cq4e5xOVI5cKCflT_nThT5Imx47higvo4jlA/> .
@prefix np: <http://www.nanopub.org/nschema#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix npx: <http://purl.org/nanopub/x/> .
@prefix dc: <http://purl.org/dc/terms/> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

sub:Head {
  this: a np:Nanopublication;
    np:hasAssertion sub:assertion;
    np:hasProvenance sub:provenance;
    np:hasPublicationInfo sub:pubinfo .
}

sub:assertion {
  <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>
    a prov:SoftwareAgent;
    <http://www.w3.org/2000/01/rdf-schema#label> "delphisci dataset-resolvability assessor (Gemini 4 Argon)";
    prov:actedOnBehalfOf <https://orcid.org/0009-0007-4948-9192>;
    <https://w3id.org/delphi/ontology/usesModel> <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini> a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:description "The pseudo-simple-cubic diffraction pattern of KCl is a textbook structure-factor cancellation effect directly verifiable in RRUFF powder patterns and COD refinements. Because K+ and Cl- are isoelectronic with nearly equal masses, their difference reflections (odd h, k, l) nearly vanish, leaving only reflections corresponding to a simple cubic lattice of spacing a/2 with mean mass (M_KCl)/2 per lattice site.";
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    <http://www.w3.org/2000/01/rdf-schema#comment> "Proposed test with existing data: Compare the all-odd (hkl) versus all-even (hkl) X-ray structure factors F(hkl) = 4*(f_K+ +/- f_Cl-) of KCl (space group Fm-3m) using experimental diffraction patterns and atomic scattering factor tables. Confirm if the near-equality of scattering factors for isoelectronic K+ and Cl- (18 electrons each; atomic weights 39.10 and 35.45) suppresses odd-(hkl) reflections, causing the diffraction pattern to mimic a simple cubic lattice of edge a/2 containing half a KCl formula unit per pseudocell.";
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon on bragg1913s-04: resolvable-now, resolvability 0.96";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0";
    <https://w3id.org/delphi/ontology/evidenceAgainst> "Strictly, X-ray scattering amplitude depends on electron count (isoelectronic K+ and Cl- both have 18 electrons) rather than nuclear atomic weight, though in 1913 atomic weight served as the proxy";
    <https://w3id.org/delphi/ontology/hasConfidence> "0.95"^^xsd:double;
    <https://w3id.org/delphi/ontology/hasEvidence> <https://w3id.org/delphi/resource/evidence/bragg1913s-04--gemini--dataset-1>,
      <https://w3id.org/delphi/resource/evidence/bragg1913s-04--gemini--dataset-2>, <https://w3id.org/delphi/resource/evidence/bragg1913s-04--gemini--dataset-3>;
    <https://w3id.org/delphi/ontology/hasScore> "0.963"^^xsd:double;
    <https://w3id.org/delphi/ontology/hasVerdict> "resolvable-now" .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--analysis-feasibility>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-analysis-feasibility>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Analysis feasibility of bragg1913s-04 by Gemini 4 Argon: 0.95";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/analysis-feasibility";
    <https://w3id.org/delphi/ontology/hasScore> "0.95"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--data-adequacy>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-data-adequacy>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Data adequacy of bragg1913s-04 by Gemini 4 Argon: 0.95";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/data-adequacy";
    <https://w3id.org/delphi/ontology/hasScore> "0.95"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--data-existence>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-data-existence>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Data existence of bragg1913s-04 by Gemini 4 Argon: 1";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/data-existence";
    <https://w3id.org/delphi/ontology/hasScore> "1"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--discriminating-power>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-discriminating-power>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Discriminating power of bragg1913s-04 by Gemini 4 Argon: 0.95";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/discriminating-power";
    <https://w3id.org/delphi/ontology/hasScore> "0.95"^^xsd:double .
  
  <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--operationalizability>
    a <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    dc:isPartOf <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini>;
    dc:subject <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0-operationalizability>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Operationalizability of bragg1913s-04 by Gemini 4 Argon: 0.95";
    prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    <https://w3id.org/delphi/ontology/assessmentType> "dataset-resolvability/0.2.0/operationalizability";
    <https://w3id.org/delphi/ontology/hasScore> "0.95"^^xsd:double .
  
  <https://w3id.org/delphi/resource/claim/bragg1913s-04> <https://w3id.org/delphi/ontology/hasAssessment>
      <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini>, <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--analysis-feasibility>,
      <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--data-adequacy>,
      <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--data-existence>,
      <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--discriminating-power>,
      <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini--operationalizability> .
  
  <https://w3id.org/delphi/resource/evidence/bragg1913s-04--gemini--dataset-1> a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Provides KCl crystal structures (Fm-3m, a ~ 6.29 A) and reflection intensity records.";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: Crystallography Open Database (COD)";
    prov:wasDerivedFrom <https://www.crystallography.net/cod/> .
  
  <https://w3id.org/delphi/resource/evidence/bragg1913s-04--gemini--dataset-2> a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Supplies experimental powder X-ray diffraction patterns of sylvite (KCl) showing the absence/near-absence of odd-(hkl) reflections such as (111).";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: RRUFF Project";
    prov:wasDerivedFrom <https://rruff.info/> .
  
  <https://w3id.org/delphi/resource/evidence/bragg1913s-04--gemini--dataset-3> a <https://w3id.org/delphi/ontology/EvidenceItem>;
    dc:description "Provides X-ray atomic form factors (FFast) for K and Cl across momentum transfer.";
    <http://www.w3.org/2000/01/rdf-schema#label> "Candidate dataset: NIST Standard Reference Data";
    prov:wasDerivedFrom <https://www.nist.gov/srd> .
  
  <https://w3id.org/delphi/resource/model/gemini-4-argon-medium> a <https://w3id.org/delphi/ontology/LanguageModel>;
    dc:identifier "gemini-4-argon-medium";
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon" .
}

sub:provenance {
  sub:assertion prov:wasAttributedTo <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium>;
    prov:wasDerivedFrom <https://github.com/fractastical/delphisci/blob/5241dc54170fa807613109d52197d32342021641/claim-sources/crystals-and-form/assessment/raw/gemini/batch-4.json>,
      <https://w3id.org/delphi/resource/concept/dataset-resolvability-0.2.0>;
    prov:wasGeneratedBy sub:assessment .
  
  sub:assessment a prov:Activity;
    prov:qualifiedAssociation sub:assessmentPlan;
    prov:wasAssociatedWith <https://w3id.org/delphi/resource/agent/delphisci-resolvability-assessor-gemini-4-argon-medium> .
  
  sub:assessmentPlan prov:hadPlan <https://github.com/fractastical/delphisci/blob/5241dc54170fa807613109d52197d32342021641/claim-sources/crystals-and-form/README.md> .
}

sub:pubinfo {
  <https://w3id.org/delphi/resource/domain/crystals-and-form> <http://www.w3.org/2000/01/rdf-schema#label>
      "crystals-and-form" .
  
  this: dc:created "2026-11-07T03:18:24.087Z"^^xsd:dateTime;
    dc:creator <https://orcid.org/0009-0007-4948-9192>;
    dc:license <https://creativecommons.org/licenses/by/4.0/>;
    npx:hasNanopubType <https://w3id.org/delphi/ontology/LLMClaimAssessment>;
    npx:introduces <https://w3id.org/delphi/resource/assessment/bragg1913s-04--gemini>;
    <http://www.w3.org/2000/01/rdf-schema#label> "Gemini 4 Argon on bragg1913s-04: resolvable-now, resolvability 0.96";
    <https://w3id.org/delphi/ontology/domain> <https://w3id.org/delphi/resource/domain/crystals-and-form> .
  
  sub:sig npx:hasAlgorithm "RSA";
    npx:hasPublicKey "MIIBIjANBgkqhkiG9w0BAQEFAAOCAQ8AMIIBCgKCAQEAyFHtPB6p0mCjDozxlOY9CmO3nBm7Te3jFbXyLmM+G1tGe47Da0jYIbhkl9Oo1ZjxmCa3LCwlEqK8gj6hEIcL4ahW30JXh9HycfKVk1bugkzMEV15tJdTzAU3sGMFnbNsn43xY2LFLy45tApkRm5byEiM7oRRrooIdwoQKnP4Wzq/bfAoJ9qvW+MGkelyOTd1jbSt+KfmT7xKmDfWzAHddUlWwMX2QJOLxDaffOteTop6ZRgPiNmPJKA/S62Gac9XtSYT3oDkZ6/nr5cxxNLpOyxTf5FPISiCe11xYO/unYjY+mwnOfA8yhJIyx1l0O9I0vpOpn+E5TvyHJV+oSTrvwIDAQAB";
    npx:hasSignature "graU1Dv7XmLpZRAXQ8ef43hoo69svDA6/jNbLQaLE5VlUN4fVz0Zs5OGxSRN+uWdy9nPSwaxqwYEAjqCAKXqhLg0+YaNaZixK12dqeHNWTTOqaBA5sBpKj18AxjaSxSqfRWSao9VRZqtghBtH70vaiM+oRfTePAGA6No8I4ObeyAivau5XUHkN2qn4Zee5tONV174WV7ELdDOL752AKEea6AeIp38GMYAVCv1YOesesFE1QavsPkkXlHacTfrLLPvWehfZxShIWWYfhSi1Bzq5GDW28W6xqwyxynRflcjWtT/1HjSMGgXONom8znkzWvYbY5M0gafoy574HvUZzpvQ==";
    npx:hasSignatureTarget this:;
    npx:signedBy <https://orcid.org/0009-0007-4948-9192> .
}